By employing non-flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the use of lithium metal as the anode allows for higher energy density compared to traditional lithium-ion batteries. To fully realize the potential of ASSLMBs, solid-state electrolytes (SSEs) must meet several requirements.
An ideal electrolyte material is expected to possess high ionic conductivity at room temperature [81, 96, 97] Different amounts of antimony–tin oxide (ATO) additive were introduced to the NaSICON system via conventional solid-state reaction. An increase in the conductivity and a decrease of the sintering temperature to 1100°C was achieved. The
Here, we demonstrate, through the use of a composite anode based on antimony nanocrystals, that metalloids offer high and stable storage capacities of up to 330 mA h g −1 for Li-garnet all-solid-state batteries at reasonably high current
In recent years, solid-state lithium batteries (SSLBs) using solid electrolytes (SEs) have been widely recognized as the key next-generation energy storage technology due to its high safety, high energy density, long cycle life, good rate performance and wide operating temperature range.
Solid-state lithium metal batteries (SSLMBs) offer numerous advantages in terms of safety and theoretical specific energy density. However, their main components namely lithium metal anode, solid-state electrolyte, and cathode, show chemical instability when exposed to humid air, which results in low capacities and poor cycling stability.
SSEs offer an attractive opportunity to achieve high-energy-density and safe battery systems. These materials are in general non-flammable and some of them may
One of the main electrochemical characteristics of a lead-acid battery is amount of water consumption. The effect of solidification temperature on electrochemical behavior (mainly hydrogen overvoltage) of Pb–Ca–Sn–Al (0.09%, Ca; 0.9%, Sn; 0.02%, Al) and Pb–Sb–Sn (1.7%, Sb; 0.24%, Sn) alloys, which are used in making the grid of lead-acid batteries, has been
Solid-state lithium metal batteries (SSLMBs) offer numerous advantages in terms of safety and theoretical specific energy density. However, their main components namely lithium metal anode, solid-state electrolyte,
The development of sodium-ion (SIBs) and potassium-ion batteries (PIBs) has increased rapidly because of the abundant resources and cost-effectiveness of Na and K. Antimony (Sb) plays an important role in SIBs and PIBs because of its high theoretical capacity, proper working voltage, and low cost. However, Sb-based anodes have the drawbacks of
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion and sodium-ion batteries are introduced in detail along with their electrode mechanisms, synthesis, design strategies and electrochemical performance. This review aims to present a full
1 Introduction. Rechargeable lithium metal batteries (LMBs) are promising future energy storage devices due to their high output energies. [1-4] Among various candidates, solid-state lithium metal batteries are particularly attractive because replacing liquid electrolytes with solid-state electrolytes (SSEs) increases the energy density and safety of batteries.
This review discusses various antimony-based anode materials applied to potassium ion batteries from various perspectives, including material selection, structural design, and storage mechanism. Research in the frontier area is systematically summarized, and
All solid-state lithium batteries (ASSLBs) overcome the safety concerns associated with traditional lithium-ion batteries and ensure the safe utilization of high-energy-density electrodes, particularly Li metal anodes with
This alludes to the fact that greater demands lead to the innovation of material selection, design, and manufacturing processes. Materials such as solid polymer, ceramic, and glass electrolyte enable solid-state
Irrespective of its exciting properties, Sb is not an earth-abundant material. An antimony circular economy must be developed for successful use in battery technology. For this, the recovery of used antimony from batteries is going to be critical and there is no literature available on this.
Antimony (Sb) has been recognized as one of the most promising metal anode materials for sodium-ion batteries, owing to its high capacity and suitable sodiation potential. Nevertheless, the large volume variation during (de)alloying can lead to material fracture and amorphization, which seriously affects their cycling stability. In this work, we report an
With the rapid development of research into flexible electronics and wearable electronics in recent years, there has been an increasing demand for flexible power supplies, which in turn has led to a boom in research into flexible solid-state lithium-ion batteries. The ideal flexible solid-state lithium-ion battery needs to have not only a high energy density, but also
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic...
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion and sodium-ion batteries are introduced in detail along with their electrode
Nanoengineering has emerged as a critical technique for enhancing anode materials in solid-state batteries. Fuchs et al. demonstrated the potential of carbon nanotubes (CNTs) in composite anodes comprising lithium
Here, we demonstrate, through the use of a composite anode based on antimony nanocrystals, that metalloids offer high and stable storage capacities of up to 330 mA h g −1 for Li-garnet all-solid-state batteries at reasonably high current densities (e.g. 240 mA g −1) at 95 °C. The results are also compared towards standard liquid type
As battery technologies are in continuous development, and especially due to the rapid growth in vehicle electrification, which requires large (e.g., 100 s of kg) battery packs, there has been a growing demand for more efficient, reliable, and environmentally friendly materials. Solid-state post-lithium-ion batteries are considered a possible next-generation energy storage
Irrespective of its exciting properties, Sb is not an earth-abundant material. An antimony circular economy must be developed for successful use in battery technology. For this, the recovery of used antimony from batteries is
SSEs offer an attractive opportunity to achieve high-energy-density and safe battery systems. These materials are in general non-flammable and some of them may prevent the growth of Li dendrites. 13,14 There are two main categories of SSEs proposed for application in Li metal batteries: polymer solid-state electrolytes (PSEs) 15 and inorganic solid-state
This review discusses various antimony-based anode materials applied to potassium ion batteries from various perspectives, including material selection, structural design, and storage mechanism. Research in the frontier area is systematically summarized, and corresponding optimization strategies are proposed for the failure mechanisms of
Anodeless solid-state batteries have the potential to increase the energy density and safety of batteries, but they face challenges, including inhomogeneous plating of Li metal on the current collector and penetration of
By employing non-flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the use of lithium metal as the anode allows for higher energy density
Nanoengineering has emerged as a critical technique for enhancing anode materials in solid-state batteries. Fuchs et al. demonstrated the potential of carbon nanotubes (CNTs) in composite anodes comprising lithium metal. This study highlighted the transformation of dissolution kinetics from 2D to 3D in the anode, crucial for maintaining contact
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic...
In recent years, solid-state lithium batteries (SSLBs) using solid electrolytes (SEs) have been widely recognized as the key next-generation energy storage technology due
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion and sodium-ion batteries are introduced in detail along with their electrode mechanisms, synthesis, design strategies and electrochemical performance.
Researchers have been exploring a variety of new materials, including ceramics, polymers, and composites, for their potential in solid-state batteries. These materials offer advantages like better stability and safety compared to traditional liquid electrolytes. Advances in fabrication methods have also been pivotal.
The review emphasizes the criticality of considering anode materials’ compatibility with solid-state batteries (SSBs). It underlines the importance of anode stability in solid-state environments to preserve the integrity of the solid electrolyte and avert degradation.
The solid-state design of SSBs leads to a reduction in the total weight and volume of the battery, eliminating the need for certain safety features required in liquid electrolyte lithium-ion batteries (LE-LIBs), such as separators and thermal management systems [3, 19].
The field of solid electrolytes has seen significant strides due to innovations in materials and fabrication methods. Researchers have been exploring a variety of new materials, including ceramics, polymers, and composites, for their potential in solid-state batteries.
2. Solid Electrolytes: The Heart of Solid-State Batteries The gradual shift to solid electrolytes has been influenced by the prior development of conventional lithium (Li) batteries, which have traditionally employed liquid electrolytes.
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