Among various rechargeable batteries, the lithium-ion battery (LIB) stands out due to its high energy density, long cycling life, in addition to other outstanding properties. However, the capacity of LIB drops dramatically at low temperatures (LTs) below 0 °C, thus restricting its applications as a reliable power source for electric vehicles in cold climates and
In this article, we provide a brief overview of the challenges in developing lithium-ion batteries for low-temperature use, and then introduce an array of nascent battery chemistries that may be intrinsically better suited for low-temperature conditions moving forward.
Figure 3 Courbe de cycle de taux de 0,5 C de la batterie lithium-ion à température ambiante. Figure 4 Courbe de cycle du taux de 0,5 C de la batterie au lithium-ion à -10 ℃ On peut voir sur la figure que la capacité de la batterie décroît rapidement dans un environnement de -10 ° C. Après 100 cycles, la capacité n''est que de 59 mAh / g et la
The emerging lithium (Li) metal batteries (LMBs) are anticipated to enlarge the baseline energy density of batteries, which hold promise to supplement the capacity loss under low-temperature scenarios. Though being promising, the applications of LMBs at low temperature presently are still challenged, supposedly relating to the inferior
However, LIBs usually suffer from obvious capacity reduction, security
Here, we first review the main interfacial processes in lithium-ion batteries at low temperatures, including Li + solvation or desolvation, Li + diffusion through the solid electrolyte interphase and electron transport. Then, recent
Lithium (Li) ion battery has penetrated almost every aspect of human life, from portable electronics, vehicles, to grids, and its operation stability in extreme environments is becoming increasingly important. Among these, subzero temperature presents a kinetic challenge to the electrochemical reactions required to deliver the stored energy. In this work, we
An ultra-fast charging strategy for lithium-ion battery at low temperature without lithium plating. J Energy Chem, 72 (2022), pp. 442-452. View PDF View article View in Scopus Google Scholar [39] R. Huang, G. Wei, X. Zhou, J. Zhu, X. Pan, X. Wang, et al. Targeting the low-temperature performance degradation of lithium-ion batteries: a non-destructive bidirectional
This review summarizes the state-of-art progress in electrode materials, separators, electrolytes, and charging/discharging performance for LIBs at low temperatures.
This review recommends approaches to optimize the suitability of LIBs at low temperatures by employing solid polymer electrolytes (SPEs), using highly conductive anodes, focusing on improving commercial cathodes, and
Here, we first review the main interfacial processes in lithium-ion batteries at low temperatures, including Li + solvation or desolvation, Li + diffusion through the solid electrolyte interphase and electron transport. Then, recent progress on the electrode surface/interface modifications in lithium-ion batteries for enhanced low-temperature
The RB300-LT is an 8D size, 12V 300Ah lithium iron phosphate battery that requires no additional components such as heating blankets. This Low-Temperature Series battery has the same size and performance as the RB300 battery but can safely charge when temperatures drop as low as -20°C using a standard charger. The RB300-LT is an ideal choice
An electrochemical-thermal (ECT) coupled model is proposed and predicts that both battery voltage and capacity decrease with decreasing temperature, especially at sub-zero temperatures. Li-ion cell behaviors at low temperatures by a combined experimental and modeling approach were conducted.
Safe storage temperatures range from 32℉ (0℃) to 104℉ (40℃). Meanwhile, safe charging temperatures are similar but slightly different, ranging from 32℉ (0℃) to 113℉ (45℃). While those are safe ambient air temperatures, the internal temperature of a lithium-ion battery is safe at ranges from -4℉ (-20℃) to 140℉ (60℃).
Especially at low temperature, the increased viscosity of the electrolyte, reduced solubility of lithium salts, crystallization or solidification of the electrolyte, increased resistance to charge transfer due to interfacial by-products, and short-circuiting due to the growth of anode lithium dendrites all affect the performance and safety of LIBs.
In order to improve the low-temperature performance of batteries, from the perspective of the system, researchers often focus on optimizing the battery''s thermal management system to improve the temperature of the battery''s operating environment [8].
In this paper, we comprehensively summarize the recent research progress of LIB at low temperature from the perspectives of material and the structural design of battery. First, the...
Part 2. Why does low temperature affect lithium-ion battery performance? As mentioned above, lithium batteries'' working (discharging) principle is that the lithium ions in the negative electrode are dissociated through the electrolyte, pass through the battery separator, and move back to the positive electrode to generate current.
However, LIBs usually suffer from obvious capacity reduction, security problems, and a sharp decline in cycle life under low temperatures, especially below 0 °C, which can be mainly ascribed to the decrease in Li + diffusion coefficient in both electrodes and electrolyte, poor transfer kinetics on the interphase, high Li + desolvation barrier in...
This review summarizes the state-of-art progress in electrode materials, separators, electrolytes, and charging/discharging performance for LIBs at low temperatures.
In this article, we provide a brief overview of the challenges in developing lithium-ion batteries
Especially at low temperature, the increased viscosity of the electrolyte, reduced solubility of lithium salts, crystallization or solidification of the electrolyte, increased resistance to charge transfer due to interfacial by
Conventional charging methods for lithium-ion battery (LIB) are challenged with vital problems at low temperatures: risk of lithium (Li) plating and low charging speed. This study proposes a fast-charging strategy without Li plating to achieve high-rate charging at low temperatures with bidirectional chargers. The strategy combines the pulsed-heating method
However, commercially available lithium-ion batteries (LIBs) show significant performance degradation under low-temperature (LT) conditions. Broadening the application area of LIBs requires an improvement of their LT characteristics. This review examines current challenges for each of the components of LIBs (anode, cathode, and electrolyte) in
In this paper, we comprehensively summarize the recent research progress of LIB at low
An electrochemical-thermal (ECT) coupled model is proposed and predicts
In order to improve the low-temperature performance of batteries, from the perspective of the system, researchers often focus on optimizing the battery''s thermal management system to improve the
Lithium-ion batteries are in increasing demand for operation under extreme temperature conditions due to the continuous expansion of their applications. A significant loss in energy and power densities at low temperatures is still one of the main obstacles limiting the operation of lithium-ion batteries at sub-zero temperatures.
In general, from the perspective of cell design, the methods of improving the low-temperature properties of LIBs include battery structure optimization, electrode optimization, electrolyte material optimization, etc. These can increase the reaction kinetics and the upper limit of the working capacity of cells.
In short, the design of electrolytes, including aqueous electrolytes, solid electrolytes, ionic liquid electrolytes, and organic electrolytes, has a considerable improvement in the discharge capacity of lithium-ion batteries at low temperatures and greatly extends the use time of batteries at low temperatures.
When employed in an LNMO/Li battery at 0.2 C and an ultralow temperature of −50 °C, the cell retained 80.85% of its room-temperature capacity, exhibiting promising prospects in high-voltage and low-temperature applications.
Additionally, ether-based and liquefied gas electrolytes with weak solvation, high Li affinity and superior ionic conductivity are promising candidates for Li metal batteries working at ultralow temperature.
Two main approaches have been proposed to overcome the LT limitations of LIBs: coupling the battery with a heating element to avoid exposure of its active components to the low temperature and modifying the inner battery components. Heating the battery externally causes a temperature gradient in the direction of its thickness.
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